A BRANCHED-CHAIN NONACARBENE WITH A NONADECET GROUND-STATE - A STEP NEARER TO SUPERPARAMAGNETIC POLYCARBENES

Authors
NAKAMURA N INOUE K IWAMURA H
Citation
N. Nakamura et al., A BRANCHED-CHAIN NONACARBENE WITH A NONADECET GROUND-STATE - A STEP NEARER TO SUPERPARAMAGNETIC POLYCARBENES, Angewandte Chemie, International Edition in English, 32(6), 1993, pp. 872-874
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
6
Year of publication
1993
Pages
872 - 874
Database
ISI
SICI code
0570-0833(1993)32:6<872:ABNWAN>2.0.ZU;2-L
Abstract
The spin quantum number S increases from 6 to 9 on lengthening the sid e chains in 1 by a benzyl unit (n = 6 --> n = 9), a new record for a p urely organic molecule. Compound 1 was prepared by photolysis from the corresponding nonadiazo compound; the magnetic measurements were carr ied out in situ at 2 and 10 K.