MONOMERIC TRIS(ETA(2)-PYRAZOLATO)LANTHANOID COMPLEXES WITH THE BULKY 3,5-DI(TERT-BUTYL)PYRAZOLATO LIGAND

Authors
COSGRIFF JE DEACON GB GATEHOUSE BM HEMLING H SCHUMANN H
Citation
Je. Cosgriff et al., MONOMERIC TRIS(ETA(2)-PYRAZOLATO)LANTHANOID COMPLEXES WITH THE BULKY 3,5-DI(TERT-BUTYL)PYRAZOLATO LIGAND, Angewandte Chemie, International Edition in English, 32(6), 1993, pp. 874-875
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
6
Year of publication
1993
Pages
874 - 875
Database
ISI
SICI code
0570-0833(1993)32:6<874:MTCWTB>2.0.ZU;2-I
Abstract
The reaction of lanthanoids, Hg(C6F5)2, and tBu2pz (pz = pyrazolate) i n THF provided the first monomeric lanthanoid complexes of type 1 with solely chelating pz ligands. The structure on the right depicts the n eodymium complex.