HYDROGEN-BONDS AS A CRYSTAL DESIGN ELEMENT FOR ORGANIC MOLECULAR-SOLIDS WITH INTERMOLECULAR FERROMAGNETIC INTERACTIONS

Authors
HERNANDEZ E MAS M MOLINS E ROVIRA C VECIANA J
Citation
E. Hernandez et al., HYDROGEN-BONDS AS A CRYSTAL DESIGN ELEMENT FOR ORGANIC MOLECULAR-SOLIDS WITH INTERMOLECULAR FERROMAGNETIC INTERACTIONS, Angewandte Chemie, International Edition in English, 32(6), 1993, pp. 882-884
Citations number
28
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
6
Year of publication
1993
Pages
882 - 884
Database
ISI
SICI code
0570-0833(1993)32:6<882:HAACDE>2.0.ZU;2-0
Abstract
O-H ... O-N and H2C-H ... O-N hydrogen bonds determine the arrangement of the stable radical 1 in the solid state. This leads to a system wi th intermolecular ferromagnetic interactions still rare in solids comp osed of exclusively organic compounds. The experimental findings are c onsistent with properties for solid 1 predicted by MO calculations and geometric considerations.