A 2-DIMENSIONAL ICE WITH THE TOPOGRAPHY OF EDGE-SHARING HEXAGONS INTERCALATED BETWEEN CDNI(CN)4 LAYERS

Authors
PARK KM KURODA R IWAMOTO T
Citation
Km. Park et al., A 2-DIMENSIONAL ICE WITH THE TOPOGRAPHY OF EDGE-SHARING HEXAGONS INTERCALATED BETWEEN CDNI(CN)4 LAYERS, Angewandte Chemie, International Edition in English, 32(6), 1993, pp. 884-886
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Angewandte Chemie, International Edition in English → ACNP
ISSN journal
05700833
Volume
32
Issue
6
Year of publication
1993
Pages
884 - 886
Database
ISI
SICI code
0570-0833(1993)32:6<884:A2IWTT>2.0.ZU;2-B
Abstract
Fitting structurally on each other, the corrugated layers comprising a lternately [Cd-Ni(CN)4]infinity and H2O molecules are stacked in cryst als of the title compound. Two H2O molecules coordinated trans at a Cd atom connect the layers. Six H2O molecules form a network of edge-sha ring hexagons through hydrogen bonding; more H atoms are present here than can be accounted for in the formation of the maximum number of hy drogen bonds in this network.