SYNTHESIS AND CHARACTERIZATION OF ALKOXO-ARYLOXO AND CHLORO-ARYLOXO DERIVATIVES OF TITANIUM AND ZIRCONIUM

Authors
SHAH A SINGH A MEHROTRA RC
Citation
A. Shah et al., SYNTHESIS AND CHARACTERIZATION OF ALKOXO-ARYLOXO AND CHLORO-ARYLOXO DERIVATIVES OF TITANIUM AND ZIRCONIUM, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 32(7), 1993, pp. 632-635
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
32
Issue
7
Year of publication
1993
Pages
632 - 635
Database
ISI
SICI code
0376-4710(1993)32:7<632:SACOAA>2.0.ZU;2-5
Abstract
The reactions of MX4 (M = Ti, Zr; X = Cl, OPr(i)) with a number of ste rically demanding phenols, have resulted in the synthesis of novel alk oxo- and chloroaryloxides of the type MX4-n(OAr)n (where X = Cl, OPr(i ); OAr = OC6H2Me3-2, 4, 6(OAr1), OCH3Pr2i-2, 6-(OAr2), OC6H2Bu2t-2, 6- Me-4(OAr3); n = 1, 2, 3 or 4). These complexes have been characterized on the basis of IR and NMR spectral studies.