EXPERIMENTAL-STUDY OF ELEMENTARY REACTIONS OF FO RADICALS .3. REACTIONS WITH OXYGEN AND NITROGEN-ATOMS

Authors
BEDZHANYAN YR MARKIN EM POLITENKOVA GG GERSHENZON YM
Citation
Yr. Bedzhanyan et al., EXPERIMENTAL-STUDY OF ELEMENTARY REACTIONS OF FO RADICALS .3. REACTIONS WITH OXYGEN AND NITROGEN-ATOMS, Kinetics and catalysis, 33(5-6), 1992, pp. 797-801
Citations number
25
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
33
Issue
5-6
Year of publication
1992
Pages
797 - 801
Database
ISI
SICI code
0023-1584(1992)33:5-6<797:EOEROF>2.0.ZU;2-Y
Abstract
Using a combined EPR/IR LMR spectrometer under jet conditions at room temperature, we have studied the reactions: FO + O --> F + O2, FO + N --> products. We have obtained the rate constants for these reactions: k0 = (2.7 +/- 0.2).10(-11) cm3.sec-1, k(N) = (2.6 +/- 0.3).10(-11) cm 3.sec-1.