KINETICS OF THE HYDROXYETHYLATION REACTION OF N-BUTYL ALCOHOL IN A SOLVENT - A CLUSTER (MICELLAR) MODEL

Authors
STUL BY ASRIEV SD EMELYANOV VI CHESNOKOV BB
Citation
By. Stul et al., KINETICS OF THE HYDROXYETHYLATION REACTION OF N-BUTYL ALCOHOL IN A SOLVENT - A CLUSTER (MICELLAR) MODEL, Kinetics and catalysis, 33(5-6), 1992, pp. 828-831
Citations number
5
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
33
Issue
5-6
Year of publication
1992
Pages
828 - 831
Database
ISI
SICI code
0023-1584(1992)33:5-6<828:KOTHRO>2.0.ZU;2-W
Abstract
The kinetics was studied of the hydroxyethylation reaction of n-butyl alcohol in dodecane at the ethylene oxide concentration of 0.72 mole/l iter in the initial mixture. It was shown that the experimental result s are adequately described by a kinetic equation obtained taking into account the phenomenon of the autoassociation of the alcohol molecules . A dependence was obtained of the composition of the associate or the cluster molecules of n-butyl alcohol on the concentration of the solv ent.