MASS-SPECTRAL DETECTION OF UNSTABLE PRODUCTS IN THE CATALYTIC-OXIDATION OF METHANOL ON SILVER

Authors
MATVEICHUK SV NOVORODSKII BG MAKATUN VN
Citation
Sv. Matveichuk et al., MASS-SPECTRAL DETECTION OF UNSTABLE PRODUCTS IN THE CATALYTIC-OXIDATION OF METHANOL ON SILVER, Kinetics and catalysis, 33(5-6), 1992, pp. 915-918
Citations number
7
Categorie Soggetti
Chemistry Physical
Journal title
Kinetics and catalysis → ACNP
ISSN journal
00231584
Volume
33
Issue
5-6
Year of publication
1992
Pages
915 - 918
Database
ISI
SICI code
0023-1584(1992)33:5-6<915:MDOUPI>2.0.ZU;2-H
Abstract
Mass spectrometry with isotopically labelled reagents was used to dete ct hydroperoxide, methylperoxide, and methoxyl radicals in the catalyt ic oxidation of methanol on silver. A scheme involving these species w as proposed.