The process of superpolishing with Teflon laps has enabled supersmooth
[< 0. 1 nm rms) and extremely flat (lambda/100) optical surfaces to b
e produced on a large range of amorphous and crystalline optical mater
ials. Stable surface conditions and the very low wear of a Teflon lap
during polishing provide an opportunity to examine the effects of vary
ing different polishing parameters. These include sample-to-lap mismat
ch and the influence of different polishing compounds and fluid chemis
try. The results show that when large optical flats are superpolished
with Teflon laps, microroughness, subsurface damage, and scattering ca
n be minimized and reliably and consistently predicted for a wide vari
ety of optical materials, while extremely flat surfaces are simultaneo
usly achieved.