Colorimetric purity, measured as the first step from white toward the
spectrum has a V-shaped function. Purity discrimination is best near 4
00 nm, least at 570 nm and intermediate at mid-spectrum and long wavel
engths. A much flatter function occurs when colorimetric purity is mea
sured as the first step from the spectrum toward white. In this study,
we applied the formulation of chromatic discrimination thresholds mea
sured along the S-cone and M/L-cone axis to account for chromatic disc
rimination in the equiluminant plane. The modeling results show that t
he purity step from white has a 1.6 log unit calculated range, similar
to the classical data. The purity step from the spectrum is much flat
ter. The predicted range is dependent on the individual variance in ch
romatic discrimination thresholds and the luminance level. We then use
d psychophysical procedures to test the model's predictions. The resul
ting purity discrimination functions were generally in agreement with
the model. Our modeling indicates that discrepant data of colorimetric
purity can be explained with the context of discrimination models.