I. Khubeis et O. Meyer, MERCURY IMPLANTED INTO ALUMINUM - TEMPERATURE AND CONCENTRATION-DEPENDENCE OF THE SUBSTITUTIONAL COMPONENT, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 80-1, 1993, pp. 184-187
High substitutional fractions, f(s), with values up to 0.8 were measur
ed for Hg implanted into Al single crystals at 77 K with Peak concentr
ations up to 5 at.%. Annealing to 293 K leads to a decrease of f(s) fr
om 0.8 to 0.29 due to the interaction of Hg with vacancies V. Implanta
tion of Hg in Al at 77 K and at 293 K reveals an anomalous increase of
f(s) with increasing Hg concentration. For 293 K implants, a saturati
on value for f(s) of 0.29 is reached at Hg concentrations above approx
imately 1 at.%. In contrast to 77 K implants, the critical angle of Hg
is smaller than that of Al indicating Hg-V complex formation or coher
ent precipitation. Angular scan measurements at temperatures up to 365
K did not reveal any change in the shape of the dip and f(s). At room
temperature and pressure, the high dose implanted layers decompose.