Sa. Bota et al., ANALYSIS OF THE SIO2 DEFECTS ORIGINATED BY PHOSPHORUS IMPLANTATION INMOS STRUCTURES, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 80-1, 1993, pp. 612-615
Medium-dose ion implantation is widely used in CMOS technology, howeve
r unwanted effects may occur when the doping ions are implanted throug
h the thermally grown SiO2 layer. We study the effect of the P+ implan
tation in the dose range 10(11)-10(13 cm-2 and annealing treatment met
hods on the carrier trapping centres concentration in bulk SiO2 and th
e interface-state density at the SiO2-Si interface. Trapping kinetics
analysis has been performed using photoinjection as a charging tool. W
e have found a dominant electron trapping centre with a capture cross
Section of (1-2) x 10(-17) cm2 and a second electron trapping centre w
ith (1-3) x 10(-16) cm2. The density of the dominant trap has been fou
nd to be dependent on annealing treatment. These results are explained
taking into account the damage introduced by the implantation process
, which leads to the generation of carrier traps into the oxide. The i
nitial interface state density rises with increasing dose and is also
dependent upon the thermal treatment method. We also observe interface
state generation after charge injection with a generation rate value
higher than that usually found in nonimplanted structures, independent
ly of implantation parameters.