SCANNING-TUNNELING-MICROSCOPY AND TRANSMISSION ELECTRON-MICROSCOPY OFLANGMUIR-BLODGETT-FILMS OF 3 DONOR-SIGMA-ACCEPTOR MOLECULES - BDDAP-C-HETCNQ, BDDAP-C-HPTCNQ AND BDDAP-C-HBTCNQ
P. Wang et al., SCANNING-TUNNELING-MICROSCOPY AND TRANSMISSION ELECTRON-MICROSCOPY OFLANGMUIR-BLODGETT-FILMS OF 3 DONOR-SIGMA-ACCEPTOR MOLECULES - BDDAP-C-HETCNQ, BDDAP-C-HPTCNQ AND BDDAP-C-HBTCNQ, Synthetic metals, 57(1), 1993, pp. 3824-3829
Langmuir-Blodgett films of three very similar molecules, BBDAP-C-HETCN
Q (1), BDDAP-C-HPTCNQ (2), and BDDAP-C-HBTCNQ (3) were studied by STM
and TEM. The areas per molecule and the STM resolution decrease in the
order 1 to 2 to 3: it seems that disorder increases, and that a trivi
al change in the sigma bridge linking the medium electron donor BDDAP
to the strong electron acceptor TCNQ in these three molecules causes m
ajor changes in the films.