RHODIUM CARBENOID MEDIATED CYCLIZATIONS - INTRAMOLECULAR CYCLOPROPANATION AND C-H INSERTION REACTIONS DERIVED FROM TYPE-II O-ALKYNYL SUBSTITUTED ALPHA-DIAZOACETOPHENONES

Authors
MUELLER PH KASSIR JM SEMONES MA WEINGARTEN MD PADWA A
Citation
Ph. Mueller et al., RHODIUM CARBENOID MEDIATED CYCLIZATIONS - INTRAMOLECULAR CYCLOPROPANATION AND C-H INSERTION REACTIONS DERIVED FROM TYPE-II O-ALKYNYL SUBSTITUTED ALPHA-DIAZOACETOPHENONES, Tetrahedron letters, 34(27), 1993, pp. 4285-4288
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
27
Year of publication
1993
Pages
4285 - 4288
Database
ISI
SICI code
0040-4039(1993)34:27<4285:RCMC-I>2.0.ZU;2-Q
Abstract
The Rh(II) catalyzed reaction of alkynyl substituted diazo ketones giv es rise to products derived from migration of the metal to the remote acetylenic carbon atom.