SULFENYL CHLORIDE CHEMISTRY - SULFUR TRANSFER TO DOUBLE-BONDS

Authors
ABUYOUSEF IA HYNES RC HARPP DN
Citation
Ia. Abuyousef et al., SULFENYL CHLORIDE CHEMISTRY - SULFUR TRANSFER TO DOUBLE-BONDS, Tetrahedron letters, 34(27), 1993, pp. 4289-4292
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
27
Year of publication
1993
Pages
4289 - 4292
Database
ISI
SICI code
0040-4039(1993)34:27<4289:SCC-ST>2.0.ZU;2-8
Abstract
When triphenylmethanesulfenyl chloride (1) (or its thio homolog 2) are treated with various bicycles, 1,2 addition reactions take place. Fin al products occur via an episulfide intermediate. The stereochemistry of addition has been determined by x-ray analysis. Finally, evidence h as been obtained for the delivery of diatomic sulfur, likely via inter mediate 3.