HOMOGENEOUS CATALYSIS - USE OF THE [TICP2(CF3SO3)2] CATALYST FOR THE SAKURAI REACTION OF ALLYLIC SILANES WITH ORTHOESTERS, ACETALS, KETALS AND CARBONYL-COMPOUNDS
Tk. Hollis et al., HOMOGENEOUS CATALYSIS - USE OF THE [TICP2(CF3SO3)2] CATALYST FOR THE SAKURAI REACTION OF ALLYLIC SILANES WITH ORTHOESTERS, ACETALS, KETALS AND CARBONYL-COMPOUNDS, Tetrahedron letters, 34(27), 1993, pp. 4309-4312
The effectiveness of the [TiCp2(CF3SO3)2] catalyst for the Sakurai rea
ction has been explored for a variety of allylic silanes reacting with
orthoesters, acetals, ketals, aldehydes and ketones.