HOMOGENEOUS CATALYSIS - USE OF THE [TICP2(CF3SO3)2] CATALYST FOR THE SAKURAI REACTION OF ALLYLIC SILANES WITH ORTHOESTERS, ACETALS, KETALS AND CARBONYL-COMPOUNDS

Citation
Tk. Hollis et al., HOMOGENEOUS CATALYSIS - USE OF THE [TICP2(CF3SO3)2] CATALYST FOR THE SAKURAI REACTION OF ALLYLIC SILANES WITH ORTHOESTERS, ACETALS, KETALS AND CARBONYL-COMPOUNDS, Tetrahedron letters, 34(27), 1993, pp. 4309-4312
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
27
Year of publication
1993
Pages
4309 - 4312
Database
ISI
SICI code
0040-4039(1993)34:27<4309:HC-UOT>2.0.ZU;2-3
Abstract
The effectiveness of the [TiCp2(CF3SO3)2] catalyst for the Sakurai rea ction has been explored for a variety of allylic silanes reacting with orthoesters, acetals, ketals, aldehydes and ketones.