INFLUENCE OF STERIC CROWDING ON THE ELECTROCHEMICAL REDUCTION OF SUBSTITUTED TERTIARY PYRIDYLCARBOXAMIDES IN AQUEOUS ACIDIC MEDIUM

Authors
LARGERON M AUZEIL N BACQUE E FLEURY MB
Citation
M. Largeron et al., INFLUENCE OF STERIC CROWDING ON THE ELECTROCHEMICAL REDUCTION OF SUBSTITUTED TERTIARY PYRIDYLCARBOXAMIDES IN AQUEOUS ACIDIC MEDIUM, Perkin transactions. 2, (3), 1997, pp. 495-501
Citations number
20
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Perkin transactions. 2 → ACNP
ISSN journal
03009580
Issue
3
Year of publication
1997
Pages
495 - 501
Database
ISI
SICI code
0300-9580(1997):3<495:IOSCOT>2.0.ZU;2-8
Abstract
In order to assess the influence of the steric crowding on the electro chemical reduction of pyridycarboxamides, we have studied a series of tertiary aromatic or alicyclic pyridylcarboxamides. We have shown that increasing steric hindrance at the amide nitrogen led to the producti on of either tetrahydropyridine or aminomethylpyridine.