KINETICS OF DESOLVATION FROM CRYSTALLINE INCLUSION-COMPOUNDS OF A DIOL HOST WITH METHANOL AND ETHANOL

Citation
Sa. Bourne et al., KINETICS OF DESOLVATION FROM CRYSTALLINE INCLUSION-COMPOUNDS OF A DIOL HOST WITH METHANOL AND ETHANOL, Perkin transactions. 2, (3), 1997, pp. 585-587
Citations number
9
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
03009580
Issue
3
Year of publication
1997
Pages
585 - 587
Database
ISI
SICI code
0300-9580(1997):3<585:KODFCI>2.0.ZU;2-M
Abstract
The crystal structures of the inclusion compounds of (hydroxydiphenylm ethyl)-2,2-dimethyl-1,3-dioxolane with methanol and ethanol have been elucidated, Their isothermal kinetics of desolvation have been studied , Both lose the guest in a single deceleratory step, and a kinetic mod el based on a diffusion mechanism was found to be the best description for this process.