Jr. Brown et G. Deschenes, CHARACTERIZATION OF THE GOLD COMPLEX ADSORBED ON ACTIVATED CARBON FROM CHLORIDE, CYANIDE AND THIOUREA SOLUTIONS, CIM bulletin, 86(967), 1993, pp. 79-87
X-ray Photoelectron Spectroscopy (XPS), X-ray Diffraction (XRD) and El
ectron Probe Micro-Analysis (EPMA) were used to characterize chemicall
y the gold complex adsorbed on activated carbon from a solution contai
ning 102 mg/L Au and 0.5 g/L thiourea. This paper also considers the g
old chloride and the gold cyanide systems. The results indicate gold i
s adsorbed on activated carbon from the thiourea solution as the gold
(I) thiourea complex, i.e. Au[CS(NH2)2]2+. Other gold species such as
metallic gold were not detected on the carbon support. These results a
lso suggest the elution of the gold (I) thiourea complex can be perfor
med with high recovery.