A. Soldatov et O. Andersson, THERMAL-CONDUCTIVITY OF PRESSURE POLYMERIZED C-60, Applied physics A: Materials science & processing, 64(3), 1997, pp. 227-229
We have studied the kinetics of C-60 polymerization in the temperature
interval 450-500 K at pressures below 1 GPa by measurements of the ti
me dependence of the thermal conductivity. It has been found at 450 K
that the polymerization process at 0.8 GPa is slower than the reverse
transformation from ''polymeric'' to ''monomeric'' phase at 0.08 GPa.
The thermal conductivity lambda of polymerized C-60 was measured in th
e temperature range 100-430 K and found to increase with increasing te
mperature, which reflects strong phonon scattering. Both the presence
of non-bonded C-60 molecules and a high degree of structural disorder
in the crystalline lattice of the polymeric phase might be responsible
for the behaviour of lambda(T). The results for lambda(T) are qualita
tively similar to those reported previously for C-60 polymerized at hi
gher p, T but an order of magnitude smaller.