THERMAL-CONDUCTIVITY OF PRESSURE POLYMERIZED C-60

Citation
A. Soldatov et O. Andersson, THERMAL-CONDUCTIVITY OF PRESSURE POLYMERIZED C-60, Applied physics A: Materials science & processing, 64(3), 1997, pp. 227-229
Citations number
21
Categorie Soggetti
Physics, Applied
ISSN journal
09478396
Volume
64
Issue
3
Year of publication
1997
Pages
227 - 229
Database
ISI
SICI code
0947-8396(1997)64:3<227:TOPPC>2.0.ZU;2-A
Abstract
We have studied the kinetics of C-60 polymerization in the temperature interval 450-500 K at pressures below 1 GPa by measurements of the ti me dependence of the thermal conductivity. It has been found at 450 K that the polymerization process at 0.8 GPa is slower than the reverse transformation from ''polymeric'' to ''monomeric'' phase at 0.08 GPa. The thermal conductivity lambda of polymerized C-60 was measured in th e temperature range 100-430 K and found to increase with increasing te mperature, which reflects strong phonon scattering. Both the presence of non-bonded C-60 molecules and a high degree of structural disorder in the crystalline lattice of the polymeric phase might be responsible for the behaviour of lambda(T). The results for lambda(T) are qualita tively similar to those reported previously for C-60 polymerized at hi gher p, T but an order of magnitude smaller.