INTERMEDIATES AND ISOMERS IN THE SUBSTITUTION OF COBALT CARBONYL HYDRIDE WITH TERTIARY PHOSPHORUS LIGANDS

Authors
BARTIK T KRUMMLING T HAPP B SIEKER A MARKO L BOESE R UGO R ZUCCHI C PALYI G
Citation
T. Bartik et al., INTERMEDIATES AND ISOMERS IN THE SUBSTITUTION OF COBALT CARBONYL HYDRIDE WITH TERTIARY PHOSPHORUS LIGANDS, Catalysis letters, 19(4), 1993, pp. 383-389
Citations number
35
Categorie Soggetti
Chemistry Physical
Journal title
Catalysis letters → ACNP
ISSN journal
1011372X
Volume
19
Issue
4
Year of publication
1993
Pages
383 - 389
Database
ISI
SICI code
1011-372X(1993)19:4<383:IAIITS>2.0.ZU;2-D
Abstract
Mono- and disubstitution of HCO(CO)4 with tertiary phosphines and phos phites was studied by IR and H-1-NMR spectroscopy. It was found that t hese substitutions proceed through phosphonium tetracarbonylcobaltate intermediates, leading to a mixture of isomers. The crystal and molecu lar structure of trans-HCO(CO)3[P(O-p-C6H4Ph)3] was determined by X-ra y diffraction.