Sjc. Irvine et J. Bajaj, IN-SITU CHARACTERIZATION TECHNIQUES FOR MONITORING AND CONTROL OF VPEGROWTH OF HG1-XCDXTE, Semiconductor science and technology, 8(6), 1993, pp. 860-871
In situ diagnostic techniques are broadly divided into two categories,
those involving an electron probe or reflected beam and those relying
just on photon beams. The former, such as RHEED, XPS, AES and UPS, ca
n be used in MBE monitoring but are not suitable for the high-pressure
environment of MOVPE. Optical diagnostic techniques such as ellipsome
try, laser reflectometry, quasielectric light scattering, reflection d
ifference spectroscopy (RDS) and infrared reflection-absorption spectr
oscopy (IRRAS) can be used as an in situ monitor in both UHV and high-
pressure growth chambers. These are compared with the electron beam te
chniques and some analogues are established in terms of the properties
of the growing films. The in situ monitoring of MCT growth is helping
to improve layer quality and reproducibility. Some specific examples
are discussed, including the potential for in situ feedback control.