POLYALKOXYPHOSPHAZENES BY ROOM-TEMPERATURE POLYMERIZATION OF AN ELECTRONEGATIVE PHOSPHORANIMINE MONOMER

Authors
CHAPMAN RD WELKER MF KREUTZBERGER CB
Citation
Rd. Chapman et al., POLYALKOXYPHOSPHAZENES BY ROOM-TEMPERATURE POLYMERIZATION OF AN ELECTRONEGATIVE PHOSPHORANIMINE MONOMER, Journal of inorganic and organometallic polymers, 6(3), 1996, pp. 267-275
Citations number
20
Categorie Soggetti
Polymer Sciences
Journal title
Journal of inorganic and organometallic polymers → ACNP
ISSN journal
10530495
Volume
6
Issue
3
Year of publication
1996
Pages
267 - 275
Database
ISI
SICI code
1053-0495(1996)6:3<267:PBRPOA>2.0.ZU;2-B
Abstract
A new electronegative alkoxyphosphazene monomer, -dinitropropoxy)N-(tr imethylsilyl)phosphoranimine, has been prepared. The anionic polymeriz ation of this monomer occurs even at room temperature, in contrast to that of previous trialkoxy-N-(trimethylsilyl)phosphoranimines, which r equire elevated temperatures for efficient polymerization. The new pol ymerizations occur via catalysis by tetra-n-butylammonium fluoride or even by adventitious moisture.