Y. Okada et al., RELATIONSHIP BETWEEN GROWTH-CONDITIONS, NITROGEN PROFILE, AND CHARGE TO BREAKDOWN OF GATE OXYNITRIDES GROWN FROM PURE N2O, Applied physics letters, 63(2), 1993, pp. 194-196
We studied the relationship between the growth conditions, the nitroge
n profile, and the charge to breakdown of N2O oxynitrides grown in a R
TP and in a conventional furnace. RTP oxynitride shows nitrogen accumu
lation at the Si/SiO2 interface. On the other hand, furnace oxynitride
shows almost uniform nitrogen distribution in the bulk, resulting in
poor charge to breakdown characteristics. We find that two-step oxynit
ridation processes provide nitrogen accumulation at the Si/SiO2 interf
ace and result in better electrical properties than those of one-step
oxynitrides.