Measurements of photoluminescence (PL) and Hall effect have been made
on Sb-doped p-GaSe. The PL spectra at 77 K are dominated by two new em
ission bands at 1.75 and 1.66 eV. The 1.66 emission band is enhanced b
y adding Sb. The temperature dependences of the peak energy and the PL
intensity of 1.66 eV emission band reveal that the acceptor level is
located at 0. 09 eV above the valence band. The deep acceptor level lo
cated at 0.57 eV above the valence band is detected by using Hall effe
ct measurements. We found that the deep acceptor level is probably ass
ociated with defects or defect complexes formed by Sb atoms in the int
erlayer.