KINETIC PARAMETERIZATION OF TRANSITIONS AND REACTIONS IN FOOD SYSTEMSFROM ISOTHERMAL AND NONISOTHERMAL DSC TRACES

Citation
M. Riva et A. Schiraldi, KINETIC PARAMETERIZATION OF TRANSITIONS AND REACTIONS IN FOOD SYSTEMSFROM ISOTHERMAL AND NONISOTHERMAL DSC TRACES, Thermochimica acta, 220, 1993, pp. 117-130
Citations number
15
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00406031
Volume
220
Year of publication
1993
Pages
117 - 130
Database
ISI
SICI code
0040-6031(1993)220:<117:KPOTAR>2.0.ZU;2-2
Abstract
When reactions and/or transitions take place within a food system, i.e . in the presence of a number of components, their kinetic parameteriz ation can be approached by careful analysis of isothermal DSC traces. Even when the signal is relatively smooth, a ''fine structure'' can be observed. This can be used in numerical manipulations if the original trace is in digital format. Some simple expressions are proposed for the determination of kinetic parameters from isothermal and non-isothe rmal scans. The case of consecutive reactions is also considered.