PREPARATION AND CHARACTERIZATION OF TRIS(1,10-PHENANTHROLINE) TECHNETIUM(III)

Authors
KREMER C KREMER E
Citation
C. Kremer et E. Kremer, PREPARATION AND CHARACTERIZATION OF TRIS(1,10-PHENANTHROLINE) TECHNETIUM(III), Journal of radioanalytical and nuclear chemistry, 175(6), 1993, pp. 445-453
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Analytical","Nuclear Sciences & Tecnology
Journal title
Journal of radioanalytical and nuclear chemistry → ACNP
ISSN journal
02365731
Volume
175
Issue
6
Year of publication
1993
Pages
445 - 453
Database
ISI
SICI code
0236-5731(1993)175:6<445:PACOTT>2.0.ZU;2-0
Abstract
The [Tc(phen)3](PF6)3 complex has been synthesized by ligand substitut ion on [Tc(tu)6]3+. The reaction proceeds quickly in aqueous solution. A pure compound is obtained with 40% yield. It was characterized by T c elemental analysis, cerimetric titration, conductometry and electrop horesis. The corresponding spectroscopic properties (UV, Vis, IR and N MR) are also reported and discussed.