H. Natter et R. Hempelmann, NANOCRYSTALLINE COPPER BY PULSED ELECTRODEPOSITION - THE EFFECTS OF ORGANIC ADDITIVES, BATH TEMPERATURE, AND PH, Journal of physical chemistry, 100(50), 1996, pp. 19525-19532
The nanostructure of nano-metals prepared by pulsed electrodeposition
is to a large extent adjustable by the appropriate choice of physical
and chemical parameters of the electrolysis. For nano-Pd we have demon
strated recently how the shape of the current pulses influences the gr
ain size. Here we focus on the effects of organic additives, bath temp
erature, and pH on the nanostructure of nano-copper.