H. Du et al., STUDY OF PHOTOREACTION IN DICHROMATED GELATIN BY LASER PHOTOACOUSTIC TECHNIQUE, Applied physics. B, Lasers and optics, 64(3), 1997, pp. 377-381
An experimental method to study the photochemical reaction in solid-st
ate dichromated gelatin during exposure is proposed, in which two lase
r sources with different wavelengths are used to induce photoreaction
and to excite photoacoustic signal, respectively. This method is to ob
tain the real-time characteristics during the formation of the photore
action product. The curve is fitted using the Rosencwaig-Gersho (R-G)
theory and chemical kinetics. The reaction order and the rate of react
ion may be obtained by fitting the parameters. The results show that p
hotochemical reaction in dichromated gelatin conforms to the mechanism
suggested by Watanable-Westheimer, and the photosensitivity of the sa
mples, prepared under different conditions, is dependent on the initia
l concentration of photoactive ions.