The authors have developed a low-temperature process for selective dep
osition of silicon by mercury sensitized photochemical vapor depositio
n (Photo-CVD) without using ultraclean technology. It was found that h
ydrogen radical pretreatment was required to obtain selective depositi
on. There was an incubation period f or not only SiO2 surface but also
Si surface. It was confirmed that mercury sensitized Photo-CVD is a p
romising method for selective deposition process at low temperature us
ing large-area glass substrate.