SYNTHESIS AND CHARACTERIZATION OF BIS(AMI NE) IRON(II) PORPHYRINS

Authors
ZHONG XH FENG YY HUANG JS SHEN PW
Citation
Xh. Zhong et al., SYNTHESIS AND CHARACTERIZATION OF BIS(AMI NE) IRON(II) PORPHYRINS, Gaodeng xuexiao huaxue xuebao, 18(3), 1997, pp. 357-359
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Gaodeng xuexiao huaxue xuebao → ACNP
ISSN journal
02510790
Volume
18
Issue
3
Year of publication
1997
Pages
357 - 359
Database
ISI
SICI code
0251-0790(1997)18:3<357:SACOBN>2.0.ZU;2-V
Abstract
A series of bis(amine) iron(Il) porphyrin Fe(II)TPP(NH(2)R)(2) complex es (NH(2)R =PhNHB(2) C6H11NH2, n-BuNH(2), PhCH(2)NH(2), NHMe(2); TPP=d ianion of meso-tetraphenylporphyrin) were prepared. by the reduction o f Fe(II) porphyrins with the corresponding amine in an antiformin syst em in air as well as by the sodium borohydride reduction method, respe ctively. The complexes were characterized by UV-Vis, IR and elementary analysis, and some important properties of them were discussed.