This article reviews the available modeling and experimental data on h
ydrogen production during melt-water interactions once melt contacts r
esidual coolant in the lower head of a light-water reactor (LWR). The
two principal limiting mechanisms, oxygen diffusion through an oxide l
ayer and hydrogen diffusion through the steam film at the metal surfac
e, are described. An appendix contains a description and discussion of
the available experimental data in this area. A detailed discussion o
f the extant modeling is given. The models vary greatly in their sophi
stication, with the most developed being applicable to the case of mel
t droplets in film boiling, where the models have provided useful insi
ghts into the factors governing hydrogen production. Scoping calculati
ons are reported for the configurations of coarse mixing, a stratified
melt pool under water, and a steam explosion. These suggest that addi
tional oxidation of core material in the lower head will add a few per
cent to the total hydrogen production. However, no firm upper limit on
hydrogen production can be supported on the basis of the available da
ta and models.