Pn. Humphreys et al., INFLUENCE OF PLASTICS ON THE ANAEROBIC-DIGESTION OF HIGH CELLULOSIC CONTENT WASTE MATERIALS, Environmental technology, 14(7), 1993, pp. 665-671
Amongst the different low level radioactive wastes (LLW) the high cell
ulosic stream is the most common. This waste stream consists of paper,
wood and a variety of plastics. The presence of these plastics alter
the degree of anaerobic digestibility. A kinetic study on the anaerobi
c digestion of synthetic LLW containing various types of plastics (Pol
ythene, Latex, Neoprene and PVC) was carried out batchwise over a peri
od of 128 days. The results showed biogas production from the anaerobi
c process to follow a first order kinetic reaction. Experimental data
pairs, namely the biogas volume yielded (G) and time (t), fitted the e
quation: G = G(m)[1-exp(-K0t)]. The theoretical ultimate biogas produc
tion (G(m)) and the specific rate constant, K0, were determined from e
xperimental data. The rates of reaction, as described by the constant
K0, were shown to be influenced by the presence of both the plastic an
d rubber components; reasons for this are postulated. No significant d
ifferences were found in total gas production and as such is consisten
t with the basic kinetic theory proposed.