J. Flock et Kh. Koch, SPECTROPHOTOMETRIC DETERMINATION OF FE(II) AND TOTAL IRON WITH 2,4,6-TRI(2'-PYRIDYL)-1,3,5-TRIAZINE IN IRON-ORES AND RELATED INDUSTRIAL-PRODUCTS, Fresenius' journal of analytical chemistry, 346(6-9), 1993, pp. 667-670
The complexing of Fe(II) with 2,4,6-tri(2'-pyridyl)1,3,5-triazine in t
he presence of Fe(III) represents a rapid alternative to the usual met
hods and provides good sensitivity. The results show that this method
can also be used with very different Fe(II) or Fe(III) contents. The a
pplication described for the automatic determination of Fe(II) in ores
and sinter with the continuous flow technique shows that this method
can also be used in connection with automated systems. However, partic
ular attention must be paid here to the fact that the working conditio
ns have to be optimised for each matrix.