S. Keller et al., QUALITY-CONTROL OF FOOD WITH NEAR-INFRARED-EXCITED RAMAN-SPECTROSCOPY, Fresenius' journal of analytical chemistry, 346(6-9), 1993, pp. 863-867
The former considerable handicap of Raman spectroscopy in the visible
range, the disturbing fluorescence of impurities, has now been elimina
ted: Raman spectra are excited by light quanta of the near-infrared ra
nge; their energy, however, is too small to excite fluorescence spectr
a. Now Raman spectroscopy can be applied to many'real world samples',
to quality control of raw material, to production and product control.
This paper gives examples of the application to food analysis. Many p
roblems can be solved without a special sample preparation, even by us
ing fibre bundles on-line at the sample site, in containers and in rea
l time for production control. The configuration and amount of C = C b
onds in lipids can be determined directly, also the nature and amount
of proteins and carbohydrates, and the composition of food products. N
atural and synthetic colours, flavours and vitamins can be detected on
TLC plates, especially if Raman scattering is enhanced by resonance.
Traces of distinct compounds can be detected by the SERS technique (th
e surface-enhanced Raman spectroscopy). The powerful new tool of analy
tical chemistry promises many useful applications and the replacement
of time-consuming traditional methods.