Gf. Gribakin et Vv. Flambaum, CALCULATION OF THE SCATTERING LENGTH IN ATOMIC-COLLISIONS USING THE SEMICLASSICAL APPROXIMATION, Physical review. A, 48(1), 1993, pp. 546-553
A simple analytical formula, a = aBAR [1 - tan pi/n-2 tan (PHI - pi/2(
n-2))], is obtained for the scattering length in atomic collisions. He
re aBAR = cos[pi/(n - 2)] {square-root 2Malpha/[hBAR(n - 2)]}2/(n-2) G
AMMA(n-3/n-2))/(GAMMA(n-1/n-2)) is the mean scattering length determin
ed by the asymptotic behavior of the potential U(r) approximately -alp
ha/R(n) (n = 6 for atom-atom scattering or n = 4 for ion-atom scatteri
ng), M is the reduced mass of the atoms, and PHI is the semiclassical
phase calculated at zero energy from the classical turning point to in
finity. The value of aBAR, the average scattering length, also determi
nes the slope of the s-wave phase shifts beyond the near-threshold reg
ion. The formula is applicable to the collisions of atoms cooled down
in traps, where the scattering length determines the character of the
atom-atom interaction. Our calculation shows that repulsion between at
oms (a > 0) is more likely than attraction with a ''probability'' of 7
5%. For the Cs-Cs scattering in the 3SIGMA(u) state, aBAR = 95.5alpha(
B) has been obtained, where a(B) is the Bohr radius. The comparison of
the calculated cross-section energy dependence with the experimental
data gives evidence for a positive value for the Cs-Cs scattering leng
th, which makes cesium Bose gas stable.