RADIOMETRIC ANALYSIS OF SILVER IN GALENA

Authors
Citation
Nr. Das et Hp. Maity, RADIOMETRIC ANALYSIS OF SILVER IN GALENA, Journal of radioanalytical and nuclear chemistry, 176(1), 1993, pp. 45-53
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Analytical","Nuclear Sciences & Tecnology
ISSN journal
02365731
Volume
176
Issue
1
Year of publication
1993
Pages
45 - 53
Database
ISI
SICI code
0236-5731(1993)176:1<45:RAOSIG>2.0.ZU;2-A
Abstract
A radiometric procedure for quantitative analysis of traces of silver in galena has been demonstrated. The mineral sample was dissolved in H NO3 (3:1) and silver present in the solution was precipitated as insol uble AgI by adding an excess amount of I-131-labeled KI solution and w as coprecipitated with zirconium hydrogen phosphate, Zr(HPO4)2, in 0.5 N H2SO4 medium. The method of radiometric analysis of silver which was estimated from the knowledge of the loss of I-131 activity in solutio n, was found to be effective in determination of the element even belo w ppb level. Applicability of the radiometric procedure in routine ana lysis or preconcentration of traces of silver in galena has been stres sed.