DETERMINATION OF THE STABILITY-CONSTANTS OF URANYL COMPLEX WITH 8-HYDROXYQUINOLINIUM SULFATE

Authors
UNAK P OZDEMIR D UNAK T
Citation
P. Unak et al., DETERMINATION OF THE STABILITY-CONSTANTS OF URANYL COMPLEX WITH 8-HYDROXYQUINOLINIUM SULFATE, Journal of radioanalytical and nuclear chemistry, 176(1), 1993, pp. 55-64
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Analytical","Nuclear Sciences & Tecnology
Journal title
Journal of radioanalytical and nuclear chemistry → ACNP
ISSN journal
02365731
Volume
176
Issue
1
Year of publication
1993
Pages
55 - 64
Database
ISI
SICI code
0236-5731(1993)176:1<55:DOTSOU>2.0.ZU;2-0
Abstract
8-Hydroxyquinoline (8-HOQ) is known as an important chelating agent fo r several metal ions. This compound is practically insoluble in water. For this reason, in this study its water soluble sulfate salt has bee n used for complexing uranyl ions and the stability constants of the c omplex have been determined. The Irving-Rosotti method computing the C alvin-Bjerrum pH-titration data, was applied. Finally, the stability c onstants of the complex formed between (8-HOQN-H)2SO4 and uranyl ions were found to be IgK1=8.25 and IgK2=4.15, the overall stability consta nt being Igbeta2=12.40.