From a detailed study of two different defects in silicon, excitonic A
uger capture is shown to be an important mechanism of the configuratio
nal change of metastable defects. A free exciton interacts with the de
fect and recombines, transferring its energy to an electron, which wil
l be emitted high up into the conduction band. This hot Auger electron
will quickly reach the bottom of the conduction band. The liberated e
nergy may excite the defect above the barrier between the two configur
ations.