Ms. Suresh et S. Sathyanarayana, TEMPERATURE-DEPENDENCE OF HYDROGEN EVOLUTION REACTION ON NICKEL-OXIDEELECTRODE IN SEALED NICKEL-CADMIUM CELLS, Journal of power sources, 45(2), 1993, pp. 247-253
The impedance of sealed nickel/cadmium cells around a cell e.m.f. of 0
.0 V was measure at five different temperatures between - 10 and + 30-
degrees-C. The results show that the behaviour is similar at all tempe
ratures. Based on the experimental results, the relation between charg
e-transfer resistance (R(ct)) and temperature (T) has been established
for the Volmer reaction. Further, the value of cathodic transfer coef
ficient (a) has been estimated.