M. Tikhomirova et al., OXYGEN AND CARBON-ISOTOPE VARIATIONS OF CARBONATES AND SILICATES FROMTHE CARBONATITE MASSIF TIKSHEOZERO (NORTHERN KARELIA), Isotopenpraxis, 28(3-4), 1993, pp. 237-250
Carbon and oxygen isotope compositions have been determined for carbon
ate minerals from different types of carbonatites (large carbonatite b
odies, veins, eruptive breccia), as well as from different temperature
classes of carbonatites (according to Samoilov [1]). It could be show
n, that only high temperature carbonatites exhibit small variations of
deltaO-18 and delta-C-13 falling in the range of ''high temperature m
antle carbonates'', whereas low temperature calcites and dolomites sho
w wide variations in deltaO-18. These changes in both isotope and mine
ral compositions of low temperature carbonatites are interpreted as a
result of repeated interaction with fluids. The oxygen isotope ratios
in most of the eruptive breccia have been changed by secondary process
es. The primary deep-seated isotope record has been preserved only in
samples, in which carbonate occurs as fine-grained calcite groundmass.
Preliminary results on oxygen isotope composition of different silica
te minerals (amphibole, magnetite, biotite, albite, apatite) indicate
isotope equilibrium for the mineral pair calcite-amphibole with isotop
e temperatures representing superimposed processes.