SYNTHESIS AND TRANSANNULAR DIELS-ALDER REACTIONS OF (E,E,E)-CYCLOTETRADECA-2,8,10-TRIENONES

Citation
Wr. Roush et al., SYNTHESIS AND TRANSANNULAR DIELS-ALDER REACTIONS OF (E,E,E)-CYCLOTETRADECA-2,8,10-TRIENONES, Tetrahedron letters, 34(28), 1993, pp. 4427-4430
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
28
Year of publication
1993
Pages
4427 - 4430
Database
ISI
SICI code
0040-4039(1993)34:28<4427:SATDRO>2.0.ZU;2-N
Abstract
(EEE)-Cyclotetradeca-2,8,10-trienones 4 and 5, prepared by intramolecu lar Horner-Wadsworth-Emmons reactions, undergo highly stereoselective transannular Diels-Alder reactions to the trans-anti-cis tricyclic ket ones 6 and 7, respectively.