ANOMALOUS BEHAVIOR OF THE GLASS-TRANSITION TEMPERATURE FOR A MIXTURE OF ALCOHOL AND AQUEOUS LICL SOLUTION

Authors
KANNO H MAEYAMA Y
Citation
H. Kanno et Y. Maeyama, ANOMALOUS BEHAVIOR OF THE GLASS-TRANSITION TEMPERATURE FOR A MIXTURE OF ALCOHOL AND AQUEOUS LICL SOLUTION, Chemical physics letters, 210(1-3), 1993, pp. 107-110
Citations number
17
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
210
Issue
1-3
Year of publication
1993
Pages
107 - 110
Database
ISI
SICI code
0009-2614(1993)210:1-3<107:ABOTGT>2.0.ZU;2-8
Abstract
Glass transition temperatures (T(g)) of mixtures of alcohol (methanol, ethanol or 1-propanol) and aqueous LiCl solution were measured as a f unction of alcohol content. Anomalous T(g) behavior was observed for a ll the solutions. Phase separation (double glass transition phenomenon ) was observed for the mixture of ethanol and aqueous LiCl solution. H ydrophobic interaction between water and alcohol molecules is consider ed to be responsible for the anomalous T(g) behavior.