DIFFUSION OF ATOMIC-HYDROGEN IN ICE-IH

Citation
Dm. Bartels et al., DIFFUSION OF ATOMIC-HYDROGEN IN ICE-IH, Chemical physics letters, 210(1-3), 1993, pp. 129-134
Citations number
17
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
210
Issue
1-3
Year of publication
1993
Pages
129 - 134
Database
ISI
SICI code
0009-2614(1993)210:1-3<129:DOAII>2.0.ZU;2-B
Abstract
We report new measurements of EPR spin relaxation times T1 and T2 for H atoms in hexagonal ice at -6-degrees-C. We find T1 = 23 +/- 3 mus, a nd T2 = 6.9 +/- 1.0 mus at this temperature, in good agreement with ex pectation based on previous experiments. Motional correlation times ha ve been calculated from these values and from previous T2 measurements for H and D atoms in isotopically mixed ice. The hopping rate deduced - 2.8 x 10(10) s-1 near the crystal melting point, implies a diffusio n rate of H atoms in ice nearly as fast as occurs in liquid water.