M. Robnik et L. Salasnich, WKB TO ALL ORDERS AND THE ACCURACY OF THE SEMICLASSICAL QUANTIZATION, Journal of physics. A, mathematical and general, 30(5), 1997, pp. 1711-1718
We perform a systematic WKB expansion to all orders for a one-dimensio
nal system with potential V(x) = U-0/ cos(2) (alpha x). We are able to
sum the series to the exact energy spectrum. Then we show that at any
finite order the error of the WKB approximation measured in the natur
al units of the mean energy level spacing does not go to zero when the
quantum number goes to infinity. Therefore we make the general conclu
sion that the semiclassical approximations fail to predict the individ
ual energy levels within a vanishing fraction of the mean energy level
spacing.