Leakage behavior and distortion of the polarization hysteresis loop in
ferroelectric thin films are analyzed by applying a totally depleted
asymmetric back-to-back Schottky model, with the Pt/Pb(Zr, Ti)O-3/Pt (
Pt/P2T/Pt) sandwich structural thin film capacitor as an example, Some
interesting phenomena resulting from the asymmetric interfaces, such
as the leakage current level, the flat-band voltage, the disclosure of
the hysteresis leap, and the change in the remanent polarization and
coercive field, as well as the vertical drift of the polarization hyst
eresis loop, are discussed in detail. The calculated results are also
verified with experiments.