This investigation was conducted to study the influence of NaOH concen
tration, formation voltage an temperature on the dissolution and imped
ance behaviour of anodic oxide films on hafnium. The stability of the
oxide decreases with increasing NaOH concentration, film thickness and
temperature. The dissolution rate coefficient, activation energy and
the angle theta were calculated. The impedance behaviour of the anodiz
ed hafnium surface was found to be purely capacitive under various con
ditions.