LIFTOFF-TECHNIQUE OF SINGLE-CRYSTAL DIAMOND PLATES - STUDY OF THE LATTICE DAMAGE OF THE IMPLANTED SUBSTRATES AND THE CRYSTALLINE QUALITY OFTHE HOMOEPITAXIAL FILMS BY ION CHANNELING
R. Samlenski et al., LIFTOFF-TECHNIQUE OF SINGLE-CRYSTAL DIAMOND PLATES - STUDY OF THE LATTICE DAMAGE OF THE IMPLANTED SUBSTRATES AND THE CRYSTALLINE QUALITY OFTHE HOMOEPITAXIAL FILMS BY ION CHANNELING, DIAMOND AND RELATED MATERIALS, 6(1), 1997, pp. 149-152
Diamond substrates were deeply implanted by 4.5 MeV O+. The doses were
in the range of 2.5 x 10(16) up to 8.0 x 10(17) at. cm(-2). After ann
ealing at 1200 degrees C, homoepitaxial diamond films were deposited o
nto the substrates. The surface films were then removed by selective e
tching of the ion-damaged layer at 580 degrees C in flowing air. This
process was repeated with the remaining substrates. The lattice damage
of the substrates and the crystalline quality of the homoepitaxial fi
lms were investigated by ion channelling at following process steps: (
0) before implantation; (1) after implantation; (2) after annealing; (
3) after deposition; (4) after the liftoff-step; and (5) after the sec
ond deposition step. The channelling analyses proved that it is possib
le to deposit high-quality diamond onto the ion-damaged substrates and
to repeat the liftoff-technique without additional process steps such
as, e.g., polishing the substrates after removing the epitaxial films
.