Sk. Dey et al., KINETICS AND REDUCTION CHARACTERISTICS OF HEMATITE-NONCOKING COAL MIXED PELLETS UNDER NITROGEN GAS ATMOSPHERE, ISIJ international, 33(7), 1993, pp. 735-739
Hematite-noncoking coal mixed pellets were reduced isothermally at 900
, 950, 1 000, 1 025 and 1 050-degrees-C under constant flow rate of ni
trogen gas. The surface characteristic of the reduced pellets for diff
erent time-temperature schedule were examined by a Scanning Electron M
icroscope (SEM). Analysis of the data and examination of the SEM micro
photographs revealed that the mechanism associated with the reduction
changed with increasing temperature and fractional reaction. Activatio
n energy values of the reduction at different levels of fractional rea
ction were calculated with the help of an Integration Method. The effe
ct of Carbon/Hematite molar ratio on the extent of the reduction was a
lso investigated. It was found that at temperatures 900 to 1 000-degre
es-C fractional reaction increased with increasing carbon content up t
o a critical value of the ratio and then decreased. At temperatures ab
ove 1 000-degrees-C fractional reaction increased linearly with increa
sing carbon content.