Rtm. Dobbe et Is. Oen, SULFOSALT MINERALOGY AND PARAGENETIC RELATIONS IN ZN-PB ORES FROM TUNABERG, BERGSLAGEN, SWEDEN, Neues Jahrbuch fur Mineralogie. Abhandlungen, 165(2), 1993, pp. 123-142
The high-grade metamorphic stratabound zinc-lead sulphide deposits of
Tunaberg, Bergslagen, Sweden, are hosted by metatuffites, graphite sla
tes and skarn-altered marbles. Galena-rich ores contain Ag-Sb-bearing
galena with two groups of sulphosalts: A) early Cu-Pb-Sb-sulphosalts (
boulangerite, meneghinite, bournonite, manganoan jamesonite) occurring
as up to 1 mm tabular or acicular crystals in early galena, and B) la
te Cu-Ag-Sb-sulphosalts (Ag- and high-Ag-tetrahedrite, pyrargyrite, po
lybasite, stephanite, diaphorite and andorite) occurring as anhedral i
nclusions and as replacement rims and caps on the Cu - Pb - Sb - sulph
osalts; Ag - Bi-bearing galena occurs associated with bismuthian meneg
hinite and late Ag-Bi-sulphosalts of matildite and gustavite. The Tuna
berg Zn - Pb ores crystallized from relatively Ag - Bi - Sb-rich, Zn-P
b-Cu-Co-Ni-Fe-S-bearing metamorphogenic hydrothermal solutions, and is
associated with formation of sillimanite-muscovite in hydrothermally
altered metatuffites and of Cu - Co - sulphide skarn in marbles. Textu
ral and mineralogical data suggest crystallization of the early galena
- Pb - Sb - sulphosalt assemblages at temperatures of about 500-degre
es-C. Reaction of the Pb-Sb-sulphosalts with Ag-Cu-enriched residual s
olutions caused replacement of Pb-Sb-sulphosalts by Ag-Sb- and Cu-Ag-S
b-sulphosalts; Ag - tetrahedrite is replaced by high-Ag - tetrahedrite
, pyrargyrite and polybasite at temperatures down to below 190-degrees
-C. The paragenetic sequence reflects a differentiation trend from Pb-
rich to Cu - Ag-rich Sb - Bi-bearing solutions.